Publications

 2017

Sumit Saha, Deok-Hie Park, Danielle C. Hutchison, Morgan R. Olsen, Lev N. Zakharov, David Marsh, Sara-Goberna-Ferrón, Ryan T. Frederick, J. Trey Diulus, Nizan Kenane, Gregory S. Herman, Darren W. Johnson, Douglas A. Keszler, May Nyman (2017) Alkyltin Keggin Clusters Templated by Na. Angewandte Chemie International Edition, Article ASAP: DOI: 10.1002/anie.201701703

Cory K. Perkins, Eric S. Eitrheim, Brantly L. Fulton, Lauren B. Fullmer, Christopher A. Colla, Deok-Hie Park, Anna F. Oliveri, James E. Hutchison, May Nyman, William H. Casey, Tori Z. Forbes, Darren W. Johnson, Douglas A. Keszler (2017) Synthesis of an Aluminum Hydroxide Octamer through a Simple Dissolution Method. Angewandte Chemie International Edition, Article ASAP: DOI: 10.1002/anie.201702318

Clément Falaise, Harrison A. Neal, and May Nyman. (2017) U(IV) Aqueous Speciation from the Monomer to UO2 Nanoparticles: Two Levels of Control from Zwitterionic Glycine Ligands; Inorg. Chem., Article ASAP, DOI: 10.1021/acs.inorgchem.7b00616 

Dylan J. Sures, Stefano A. Serapian, Károly Kozma, Pedro I. Molina, Carles Bo, and May Nyman. (2017) Electronic and relativistic contributions to ion-pairing in polyoxometalate model systems, Journal of Physical Chemistry Chemical Physics. 19 (13), 8715-8725 http://pubs.rsc.org/en/content/articlelanding/2017/cp/c6cp08454k#!divAbstract
 
Nunu A.G. Bandeira, Omid Sadeghi, Toby J. Woods, Yuan-Zhu Zhang, Jurgen Schnack, Kim Dunbar, May Nyman and Carles Bo. (2017) Magneto-Structural Analysis of Iron (III) Keggin Polyoxometalates, Journal of Physical Chemistry A, 121 (6), 1310-1318 http://pubs.acs.org/doi/abs/10.1021/acs.jpca.6b10763
 
Lauren B. Fullmer and May Nyman. (2017) Probing Crystallization Pathways in Group V Polyoxometalate Solutions. Journal of Cluster ScienceVolume: 28   Issue:   Special Issue: SI   Pages: 813-823   DOI: 10.1007/s10876-016-1106-8
 
David A. Marsh, Sara Goberna-Ferrón, Mary K. Baumeister, Lev N. Zakharov, May Nyman, Darren W. Johnson (2017) Ln polyoxocations: yttrium oxide solution speciation & solution deposited thin films. Dalton Transactions. 46, 947-955
DOI: 10.1039/C6DT03733J
 
 
Cory K Perkins, Ryan H Mansergh, Juan C Ramos, Charith E Nanayakkara, Deok-Hie Park, Sara Goberna-Ferrón, Lauren B Fullmer, Joshua T Arens, Maceo T Gutierrez-Higgins, Yolanda R Jones, Jonathon I Lopez, Thomas M Rowe, Danielle M Whitehurst, May Nyman, Yves J Chabal, Douglas A Keszler (2017) Low-index, smooth Al 2 O 3 films by aqueous solution process Optical Materials Express. 7(1) 273-280 https://doi.org/10.1364/OME.7.000273

 

2016

May Nyman (2016) Small-angle X-ray scattering to determine solution speciation of metal-oxo clusters.  Coordination Chemistry Reviews. Publication date: November 30 http://www.sciencedirect.com/science/article/pii/S0010854516303010

Wei Wang, Lauren B. Fullmer, Nuno A.G. Bandeira, Lev Zakharov, Carles Bo, Doug Keszler, May Nyman (2016) Crystallizing Elusive Chromium Polycations. Chem. Publication date: December 8, 2016. DOIhttp://www.sciencedirect.com/science/article/pii/S2451929416302339

Harrison Neal, Jennifer Szymanowski, Jeremy Fein, Peter Burns, and May Nyman. (2016) Benchmarking uranyl peroxide capsule chemistry in organic media. European Journal of Inorganic Chemistry. Publication date: November 4, 2016. DOI: 10.1002/ejic.201601219

Omid Sadeghi, Clément Falaise, Pedro I. Molina, Ryan Hufschmid, Charles F. Campana, Bruce C. Noll, Nigel D. Browning, and May Nyman. (2016) Chemical Stabilization and Electrochemical Destabilization of the Iron Keggin in Water. Inorganic Chemistry. 55: 11078-11088.  DOI: 10.1021/acs.inorgchem.6b01694

May Nyman (2016) Polyoxometalates and other metal-oxo clusters in nature. Springer Encyclopedia of Geochemistry. Publication date: August 30, 2016. DOI: 10.1007/978-3-319-39193-9_43-1 

Olivier Renier, Clément Falaise, Harrison Neal, Karoly Kozma, May Nyman. (2016) Closing Uranyl Polyoxometalate Capsules with Bismuth and Lead Polyoxocations. Angewandte Chemie International Edition. 55: 13480-13484. DOI: 10.1002/anie.201607151

Clément Falaise and May Nyman. (2016) The Key Role of U28 in the Aqueous Self-Assembly of Uranyl Peroxide Nanocages. Chemistry A European Journal. 22: 14678-14687. DOI:10.1002/chem.201602130

Dylan J. Sures, Sulata K. Sahu, Pedro I Molina, Alexandra Navrotsky, and May Nyman. (2016) Distinctive Interactions of Cesium and Hexaniobate in Water. Chemistry Select 1 (9): 1858-1862. DOI: 10.1002/slct.201600493
 
Pere Miró, Bess Vlaisavljevich, Adria Gil, Peter C. Burns, May Nyman, Carles Bo, C. (2016) Self‐Assembly of Uranyl–Peroxide Nanocapsules in Basic Peroxidic Environments. Chemistry A European Journal. 22: 8571-8578. DOI: 10.1002/chem.201600390
 
Todd M. Alam, Zuolei Liao, May Nyman, Jonathan R. Yates. (2016) Insight Into the Hydrogen Bonding of Uranyl Hydroxide Layers and Capsules Using 1H MAS NMR Spectroscopy. The Journal of Physical Chemistry C. 120 (19): 10675–10685 DOI: 10.1021/acs.jpcc.6b02692
 
Sara Goberna Ferron, Deok-Hie Park, Jenn M. Amador, Douglas A. Keszler, May Nyman. (2016) Amhpoteric Aqueous Hafnium Cluster Chemistry. Angewandte Chemie International Edition. 55: 6221-6224. DOI: 10.1002/anie.201601134
 
Ryan H. Mansergh, Lauren B. Fullmer, Deok-Hie Park, May Nyman, Douglas A. Keszler. (2016) Reaction Pathway: Aqueous Hexatantalate Clusters to High-Density Tantalum Oxide Nanofilms. Chemistry of Materials. 28(5): 1553-1558. DOI: 10.1021/acs.chemmater.6b00078

Dylan J. Sures, Pedro I. Molina, Pere Miro, Lev N. Zakharov, and May Nyman. (2016) Cesium salts of niobo-tungstate isopolyanions with intermediate group V -group VI character. New Journal of Chemistry. 40: 928-936. DOI: 10.1039/c5nj02914g

Tapash Deb, Lev Zakharov, Clément Falaise, and May Nyman. (2016) Structure and Solution Speciation of UIV Linked Phosphomolybate (Mo)v Clusters. Inorganic Chemistry. 55 (2): 755-761. DOI: 10.1021/acs.inorgchem.5b02229

 

2015

Cebollada,A., Vellé, A., Iglesias, M., Fullmer, L. B., Goberna-Ferron,S., Nyman, M. & Sanz Miguel, P.J., (2015) Direct X-Ray Scattering Evidence for Metal–Metal Interactions in Solution at the Molecular Level.  Angewandte Chemie. 127: 12953–12957. DOI: 10.1002/ange.201505736

Molina, P. I.; Sures, D. J.; Miro, P.; Zakharov, L. N.; Nyman, M. (2015). Bridging the opposite chemistries of tantalum and tungsten polyoxometalates. Dalton Transactions. 44: 15813-15822. DOI: 10.1039/C5DT02290H

 Jackson, M. N.; Kamunde-Devonish, M. K.; Hammann, B. A.; Wills, L. A.; Fullmer, L. B.; Hayes, S. E.; Cheong, P. H.-Y.; Casey, W. H.; Nyman, M.; Johnson, D.1W.  (2015). An overview of selected current approaches to the characterization of aqueous inorganic clusters. Dalton Transactions. 44: 16982-17006. DOI: 10.1039/C5DT01268F

Fullmer, L. B.; Mansergh, R. H.; Zakharov, L. N.; Keszler, D. A.; Nyman, M. (2015). Nb2O5 and Ta2O5 thin films from polyoxometalate precursors: A single proton makes a difference. Crystal Growth and Design. 15(8): 3885-3892. DOI: 10.1021/acs.cgd.5b00508

Nyman, M.; Fullmer, L. B. In Trends in Polyoxometalates Research; Ruhlmann, L.; Schaming, D., Eds.; Nova Science Publishers, Inc., (2015); pp. 151–170. Book Chapter PDF

Goberna-Ferrón, S., Soriano-López, J., Galán-Mascarós, J. R. and Nyman, M. (2015), Solution Speciation and Stability of Cobalt-Polyoxometalate Water Oxidation Catalysts by X-ray Scattering. Eur. J. Inorg. Chem. doi: 10.1002/ejic.201500404

Sadeghi, O; Zakharov, L. N.; Nyman, M.; (2015) Aqueous formation and manipulation of the iron-oxo Keggin ion. Science. 347 (6228), 1359-1362 doi: 10.1126/science.aaa4620 

Hou, Y.; Fast, D.B.; Ruther, R.R.; Amador, J. M.; Fullmer, L.B.; Decker, S.R.; Zakharov, L.N.; Dolgos, M.R.; Nyman, M.; (2015) "The atomic level journey from aqueous polyoxometalate to metal oxide". J. Solid State Chem., 418-425  doi:10.1016/j.jssc.2014.09.039

 

2014

Liao, Z., Deb, T., Nyman, M., (2014) Elucidating Self-Assembly Mechanisms of Uranyl-Peroxide Capsules from Monomers. Inorganic Chemistry. 53 (19), pp 10506–10513  DOI: 10.1021/ic501587g

Li, D., Simotwo, S., Nyman, M., et al., (2014) Evolution of Actinyl Peroxide Clusters U-28 in Dilute Electrolyte Solution: Exploring the Transition from Simple Ions to Macroionic Assemblies.Chemistry-A European Journal. 20(6), 1683-1690

Alam, T.M., Laio, Z., Zakharov, L.N., et al., (2014). Solid State Dynamics of Uranyl Polyoxometalates. Chemistry-A European Journal. 20(27) 8302-8307

Fullmer, L.B., Molina, P.I., Antonio, M.R., Nyman, M. (2014). Contrasting ion-association behavoir of Ta and Nb polyoxometalates. Dalton Transactions. doi:10.1039/C4DT02394C

Tiferet, E., Gil, A., Bo, C., Shvareva, T., Nyman, M., & Navrotsky, A. (2014). The Energy Landscape of Uranyl-Peroxide Species. Chemistry - A European Journal20(13), 3536. doi:10.1002/chem.201400426

Ruther, R. E., Baker, B. M., Son, J.-H., Casey, W. H., & Nyman, M. (2014). Hafnium Sulfate Prenucleation Clusters and the Hf18 Polyoxometalate Red Herring. Inorganic Chemistry53(8), 4234–4242. doi:10.1021/ic500375v

Kinnan, M. K., Creasy, W. R., Fullmer, L. B., Schreuder-Gibson, H. L., & Nyman, M. (2014). Nerve Agent Degradation with Polyoxoniobates. European Journal of Inorganic Chemistry, n/a–n/a. doi:10.1002/ejic.201400016

 Coltrin, M. E., Armstrong, A. M., Brener, I., Chow, W. W., Crawford, M. H., Fischer, A. J., … Wright, J. B. (2014). Energy Frontier Research Center for Solid-State Lighting Science: Exploring New Materials Architectures and Light Emission Phenomena. Journal of Physical Chemistry C, Ahead of Print. doi:10.1021/jp501136j

 

2013

Hou, Y., Fang, X., Kwon, K. D., Criscenti, L. J., Davis, D., Lambert, T., & Nyman, M. (2013). Computational and Experimental Characterization of a Cagelike Fe15 Polycation. European Journal of Inorganic Chemistry2013(10-11), 1780–1787. doi:10.1002/ejic.201201128

Hou, Y., Zakharov, L. N., & Nyman, M. (2013). Observing assembly of complex inorganic materials from polyoxometalate building blocks. Journal of the American Chemical Society135(44), 16651–7. doi:10.1021/ja4086484

Soylemez, E., de Boer, M. P., Sae-Ueng, U., Evilevitch, A., Stewart, T. A., & Nyman, M. (2013). Photocatalytic degradation of bacteriophages evidenced by atomic force microscopy. PLoS One8(1), e53601. doi:10.1371/journal.pone.0053601

 

2012

Nyman, M., & Burns, P. C. (2012). A comprehensive comparison of transition-metal and actinyl polyoxometalates. Chemical Society Reviews41(22), 7354–67. doi:10.1039/c2cs35136f

Nyman, M., & Alam, T. M. (2012). Dynamics of Uranyl Peroxide Nanocapsules. Journal of the American Chemical Society134(49), 20131–20138. doi:10.1021/ja308673f

Hou, Y., Rodriguez, M. A., & Nyman, M. (2012). Cation-Bonding and Protonation of the Fe4-Square Cluster. Crystal Growth & Design12(3), 1422–1431. doi:10.1021/cg2015397

Hou, Y., Alam, T. M., Rodriguez, M. a, & Nyman, M. (2012). Aqueous compatibility of group IIIA monomers and Nb-polyoxoanions. Chemical Communications, 6004–6006. doi:10.1039/c2cc31284k

Gil, A., Karhanek, D., Miro, P., Antonio, M. R., Nyman, M., & Bo, C. (2012). A Journey inside the U28 Nanocapsule. Chemistry - A European Journal18(27), 8340–8346, S8340/1–S8340/8. doi:10.1002/chem.201200801

 

Selected Publications from Sandia:

“Uranyl peroxide enhanced nuclear fuel corrosion in seawater”; Armstrong, Christopher R.; Nyman, May; Shvareva, Tatiana; Sigmon, Ginger E.; Burns, Peter C.; Navrotsky, Alex. Proceedings of the National Academy of Sciences, 109(6), 1874-1877, 2012. DOI: 10.1073/pnas.1119758109.

“The U28 Nanosphere:  What’s Inside?”  Nyman, May; Rodriguez, Mark A.; Alam, Todd M. European Journal of Inorganic Chemistry; 14, 2197-2205, 2011.  DOI: 10.1002/ejic.201001355 . cover feature

“Soluble Heteropolyniobates from the bottom of Group IA”; Hou, Yu; Nyman, May; Rodriguez, Mark A., Angew. Chem. Int. Ed., 52, 12514-12517, 2011.  DOI: 10.1002/anie.201104478. cover feature

“Polyoxoniobate Chemistry in the 21st Century”;  Nyman, May, Dalton Transac., 40(32), 8049-8058, 2011 DOI: 10.1039/c1dt10435g. cover feature

“Unique LaTaO4 Polymorph for Multiple Energy Applications”  Nyman, May; Rodriguez, Mark A.; Rohwer, Lauren E. S.; Martin, James E.; Waller, M.; Osterloh, Frank E. Chem. Mater. 21(19) 4731-4737, 2009.  DOI: 10.1021/cm9020645 Published: OCT 13 2009

“Highly Versatile Rare Earth Tantalate Pyrochlore Nanophosphors”  Nyman, May; Rodriguez, Mark A.; Shea-Rohwer, Lauren E.; Martin, James E.; Provencio, Paula P. J. Am. Chem. Soc. 131(33), 11652-11654, 2009.  DOI: 10.1021/ja903823w

“Enhanced Water Purification: A Single Atom Makes a Difference” Stewart, Tom A.; Trudell, Daniel E.; Alam Todd M.; Ohlin, C. Andre; Lawler, Christian; Casey, William H. Jett, Stephen, Nyman, May. Env. Sci Tech. 43(14), 5416-5422, 2009.  DOI: 10.1021/es803683t. featured in C&E News Science Concentrates

“Direct Observation of Contact Ion-Pair Formation in Aqueous Solution”  Antonio, Mark R.; Nyman, May; Anderson, Travis M.Angew. Chem. Int. Ed. 48(33) 6136-6140, 2009,  DOI: 10.1002/anie.200805323. cover feature

“An aqueous route to [Ta6O19]8- and solid-state studies of isostructural niobium and tantalum oxide complexes”  Anderson, Travis M.; Rodriguez, Mark A.; Bonhomme, Francois; Bixler, Joel N.; Alam, Todd M.; Nyman, May.  Dalton Transac. 40, 4517-4522,2007, DOI: 10.1039/b707636c. cover feature.

“A family of peroxo-titanate materials tailored for optimal strontium and actinide sorption”,  Nyman May; Hobbs David T.Chem. Mater. 18(26), 6425-6435, 2006;  DOI: 10.1021/cm061797h.

“A General Synthetic Procedure for Heteropolyniobates”  Nyman, May et al. Science, 297(5583), 996-998, 2002; DOI: 10.1126/science.1073979 Published.

 

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