Publications

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2022

Ashley M Hastings, Melissa Fairley, Megan C Wasson, Dario Campisi, Arup Sarkar, Zoë C Emory, Kieran Brunson, Dylan B Fast, Timur Islamoglu, May Nyman, Peter C Burns, Laura Gagliardi, Omar K Farha, Amy E Hixon, Jay A LaVerne. (2022) Role of Metal Selection in the Radiation Stability of Isostructural M-UiO-66 Metal-Organic Frameworks. Chem. Mater.  34, 18, 8403–8417. DOI: 10.1021/acs.chemmater.2c02170

Ian Colliard, Jonathan RI Lee, Christopher A Colla, Harris E Mason, April M Sawvel, Mavrik Zavarin, May Nyman, Gauthier J-P Deblonde. (2022) Polyoxometalates as ligands to synthesize, isolate and characterize compounds of rare isotopes on the microgram scale. Nature Chemistry  DOI: 10.1038/s41557-022-01018-8

Zheng Zhang, Hadiah Fattal, Tielyr D Creason, Mehran Amiri, Alexander Roseborough, Isaiah W Gilley, May Nyman, Bayram Saparov. (2022) Investigation of the Solution Chemistry of Hybrid Organic-Inorganic Indium Halides for New Material Discovery. Inorg. Chem. 61, 33, 13015-13021. DOI: 10.1021/acs.inorgchem.2c01161

Daniel E. Felton, Melissa Fairley, Ana Arteaga, May Nyman, Jay A. LaVerne, Peter C. Burns. (2022) Gamma-Ray-Induced Formation of Uranyl Peroxide Cage Clusters. Inorg. Chem. 60, 30, 11916-11922. DOI: 10.1021/acs.inorgchem.2c01657

Megan C. Wasson, Xingjie WangPatrick MelixSelim AlayogluAndrew T. Y. WolekIan ColliardFlorencia A. SonHaomiao XieEric WeitzTimur IslamogluMay NymanRandall Q. SnurrJustin M. Notestein, and Omar K. Farha. (2022) Interfacial Unit-Dependent Catalytic Activity for CO Oxidation over Cerium Oxysulfate Cluster Assemblies. ACS Appli. Mater. Interfaces , 14, 33515-33524. DOI: 10.1021/acsami.2c05937

Ian Colliard, Jessica C. Brown, and May Nyman. (2022) Metal-Oxo Cluster Formation using Ammonium and Sulfate to Differentiate MIV(Th, U, Ce) Chemistries. Inorg. Chem. DOI: 10.1021/acs.inorgchem.2c01309

Jia-Jia ChenLaia Vilà-NadalAlbert Solé-DauraGreig ChisholmTakuo MinatoChristoph BuscheTingting ZhaoBalamurugan KandasamyAlexey Y. GaninRachelle M. SmithIan ColliardJorge J. CarbóJosep M. Poblet, May Nyman, and Leroy Cronin. (2022) Effective Storage of Electrons in Water by the Formation of Highly Reduced Polyoxometalate Clusters. J. Am. Chem. Soc. 2022, 144, 8951-8960. DOI: 10.1021/jacs.1c10584

Rachelle M. Smith, Ian Colliard, Mehran Amiri, Miguel A. Galindo, and May Nyman. (2022) Silver-Cytosine-Polyoxometalate Assemblies: Assessing the Role of Polyoxometalates in Constructing Ag-DNA Suprastructures. Cryst. Growth Des. 22, 4, 2294-2306. DOI: 10.1021/acs.cgd.1c01385

Simon Greiner, Jan Hettig, Alec Laws, Katharina Baumgartner, Jenna Bustos, Prof. Dr. Ann-Christin Poppler, Dr. Adam H. Clark, Prof. Dr. May Nyman, Prof. Dr. Carsten Streb, Dr. Montaha Anjass. (2022) A General Access Route to High-Nuclearity, Metal-Functionalized Molecular Vanadium Oxides. Angewandte Chemie International Edition, 61, 9, DOI: anie.202114548

Tasnim Rahman, Enric Petrus, Mireia Segado, Nicolas Martin, Lauren Palys, Mark A. Rambaran,  C. Andre Ohlin, Carles Bo, and May Nyman (2022) Predicting solubility of ion pairs in aqueous inorganic chemistry. Angewandte Chemie International Edition.  DOI: 10.1002/anie.202117839

Tasnim Rahman, Nicolas P. Martin, Jessica K. Jenkins, Radwan Elzein, Dylan B. Fast, Rafik Addou, Gregory S. Herman, and May Nyman. (2022) Nb2O5, LiNbO3, and (Na, K)NbO3 Thin Films From High-Concentration Aqueous Nb-Polyoxometalates. Journal of Inorganic Chemistry. DOI: 10.1021/acs.inorgchem.1c03638

James A. Sommers, Lauren Palys, Nicolas P. Martin, Dylan B. Fast, Mehran Amiri, and May Nyman. (2022) Oxo-Cluster-Based Zr/HfIV Separation: Shedding LIght on a 70-Year Old Process. Journal of the American Chemical Society. DOI: 10.1021/jacs.1c13338

Rachelle M. S. Smith, Mehran Amiri, Nicolas P. Martin, Alice Lulich, Lauren N. Palys, Guomin Zhu, James J. De Yoreo, May Nyman. (2022) Solvent Driven Transformation of Zn/Cd2+-Deoxycholate Assemblies. Journal of Inorganic Chemistry.  61, 3, 1275–1286. DOI: 10.1021/acs.inorgchem.1c02245

2021

Melissa Fairley, Daniel E. Felton, Ginger E. Sigmon, Jennifer E. S. Szymanowski, Nicholas A. Poole, May Nyam, Peter C. Burns, Jay A. LaVerne (2021). Radiation-Induced Solid-State Transformations of Uranyl Peroxides. Journal of Inorganic Chemistry. 61, 2, 882-889. DOI: 10.1021/acs.inorgchem.1c02603

Simon Greiner, Jan Hettig, Alec Laws, Katharina Baumgartner, Jenna Bustos, Prof. Dr. Ann-Christin Poppler, Dr. Adam H. Clark, Prof. Dr. May Nyman, Prof. Dr. Carsten Streb, Dr. Montaha Anjass. (2021). A General Access Route to High-Nuclearity, Metal-Functionalized Molecular Vanadium Oxides. Angewandte Chemie International EditionDOI: 10.1002/ange.202114548

Xingjie Wang, Kieran Brunson, Haomiao Xie, Ian Collaird, Megan C. Wasson, Xinyi Gong, Kaikai Ma, Yufang Wu, Florencia A. Son, Karam B. Idrees, Xuan Zhang, Justin M. Notestein, May Nyman, and Omar K. Farha. (2021) Heterometallic CeIV/VV Oxo Clusters with Adjustible Catalytic Reactivities. Journal of the American Chemical Society. 143, 49, 21056-21065. DOI: 10.1021/jacs.1c11208

Lukas Reith, Carlos A. Triana, Faezeh Pazoki, Mehran Amirir, May Nyman, and Greta R. Patzke. (2021) Unraveling Nanoscale Cobalt Oxide Catalysts for the Oxygen Evolution Reaction: Maximum Performance, Minimum Effort. Journal of the American Chemical Society. 143, 37, 15022-15038. DOI: 10.1021/jacs.1c03375

Cocoro A. Nagasaka, Karoly Kozma, Kieran G. Brunson, Chris J. Russo, Todd M. Alam. May Nyman. (2021) Cs. Absorption capacity and selectivity of crystalline and amorphous Hf and Zr phosphates. Polyhedron. 202, 115199-115199. DOI: 10.1016/j.poly.2021.115199

Mehran Amiri, Dr. Nicolas P. Martin, Ching-Lei Feng, Jacob Kreager Lovio, Prof. Dr. May Nyman. (2021) Deliberate Construction of Polyoxoniobates Exploiting the carbonate Ligand. Angewandte Chemie International Edition60, 12461-12466. DOI:10.1002/ange.202017367

Ian Colliard, Jessica C. Brown, Dylan B. Fast, A Kirstin Sockwell, Amy E. Hixon, and May Nyman. (2021) Snapshots of Ce70 Toroid Assembly from Solids and Solution. Journal of the American Chemical Society. 143, 25, 9612-96-21. DOI:10.1021/jacs.1c04095 

Morgan Rose Olsen, Ian Collaird, Tasnim Rahman, Taiki C. Miyaishi, Bryan Harper, Stacey Harper, and May Nyman.(2021) Hybrid Polyoxometalate Salt Adhesion by Butyltin Functionalization. ACS Applied Materials & Interfaces. 13, 16, 19497–19506 DOI: 10.1021/acsami.1c03269

Antonio Perez-Romero, Alicia Dominguez-Martin, Simona Galli, Noelia Santamaria-Diaz, Oscar Palacios, Jose A. Dobabo, May Nyman, Miguel A Galindo. (2021) Single-stranded DNA as supramolecular template for one-dimensional palladium (II) arrays. Angewandte Chemie International Edition. DOI: 10.1002/anie.202015554

James A. Sommers, Danielle C. Hutchison, Nicolas P. Martin, Lauren Palys, Jenn M. Amador, Douglas A. Keszler, May Nyman. (2021) Differentiating Zr/HfIV Aqeous Polycation Chemistry with Peroxide Ligands.  Journal of Inorganic Chemistry. 60, 3, 1631-1640. DOI: 10.1021/acs.inorgchem.0c03128

Ian Colliard, May Nyman. (2021) CeIV70 oxosulfate rings, frameworks, supramolecular assembly and redox acivity. 60, 13, 7308-7315.  Angewandte Chemie International Edition. DOI: 10.1002/anie.20201652

2020

Danielle C. Hutchison, Rachelle M. Smith, May Nyman. (2020) Isomerization of Na-Centered Alkyltin Keggin Clusters. European Journal of Inorganic Chemistry. 44, 43-49. DOI: 10.1002/ejic.202000880

Ian Colliard, Clement Falaise, May Nyman. (2020) Bridging the Transuranics with Uranium (IV) Sulfate Aqueous Species and Solid Phases. Journal of Inorganic Chemistry. 59, 23, 17049-17057. DOI:10.1021/acs.inorgchem.0c0226

Michael A. Sinnwell, Quin R. S. Miller, Lauren Palys, Dushyant Barpage, Lili Liu, Mark E. Bowden, Yi Han, Sanjit Ghose, Maria L. Sushko, H. Todd Schaef, Wenqian Xu, May Nyman, and Praveen K. Thallapally. (2020) Molecular Intermediate in the Directed Formation of a Zeolitic Metal-Organic Framework.  Journal of the American Chemical Society. 142, 17598-17606. DOI: 10.1021/jacs.0c07862 

Nicolas P. Martin, May Nyman. (2020) Directional Bonding in Decaniobate Inorganic Frameworks.Angewandte Chemie International Edition. DOI: 10.1002/anie.202010902

Karoly Kozma, Lev N. Zakharov, May Nyman. (2020) Countercation-Controlled Nuclearity of Zr/Hf Peroxo Oxalates.Cryst. Growth Des. 20, 10, 6519-6527. DOI: 10.1021/acs.cgd.0c00713

Dylan Fast, Matthew Clark, Lauren Fulllmer, Kyle Grove, May Nyman, Brady Gibbons, Michelle Dolgos. (2020) Using simple aqueous precursors for a green synthetic pathway to potassium sodium niobate thin films. Thin Solid Films. 710, 138270. DOI: 10.1016/j.tsf.2020.138270

Ian Colliard, Prof. Dr. May Nyman. (2020) Building [UIV70(OH)36(O)64]4- Oxocluster Frameworks with Sulfate, Transition Metals, and UV. Chemistry A European Journal. 26 (54) 12481-12488. DOI: 10.1002/chem.202002403 

Tatjana N. Parac-Vogt, Jens Moons, Francisco De Axambuja, Jelena Mihailovic, Karoly Kozma, Katarina Smiljanic, Mehran Amiri, Tanja Cirkovic-Velickovic, May Nyman. (2020)  Discrete Hf18 metal-oxo cluster as a heterogeneous nanozyme for site-specifici proteolysis. Angewandte Chemie International Edition. DOI: 10.1002/anie.202001036

Wei Xu, Karoly Kozma, Tianxiang Sha, Yi-Jen Wu, May Nyman, Michael Lerner. (2020) Reversible M-M bonding by Alkaline Earth Metals(Mg, Ca, Sr, Ba) in Graphite Intercalation Compounds.  Chemistry-A European Journal. DOI: 10.1002/chem.202000504

Mehran Amiri, Nicolas P. Martin, Omid Sadeghi, and May Nyman. (2020) Bismuth for Controlled Assembly/Disassembly of Transition-Metal Oxo Clusters, Defining Reaction Pathways in Inorganic Synthesis and Nature. Inorganic Chemistry, 59(6), 3471-3481. DOI: 10.1021/acs.inorgchem.9b03646

Danielle C. Hutchison, Rebecca D. Stern, Lev N. Zakharov, Kristin A. Persson and May Nyman. (2020) Butyltin Keggin Ion with a Rare Four-Coorinate Ca Center. Inorganic Chemistry,59(5), 2900-2909. DOI10.1021/acs.inorgchem.9b03261 

Xiu-Ying Zheng, Ming-Hao Du, Mehran Amiri, May Nyman, Qiang Liu, Tao Liu, Xiang-Jian Kong, La-Sheng Long, and Lan-Sun Zheng. (2020) Atomically Precise Lanthanide-Iron-Oxo Clusters Featuring the ε-Keggin Ion. Chemistry-A European Journal, 26, 1-9. DOI:  10.1002/chem.201904636 

Ana Arteaga, Debmalya Ray, Elliot Glass, Nicolas P. Martin, Lev N. Zakarov, Laura Gagliardi, and May Nyman. (2020) The Role of the Organic Solvent Polarity in Isolating Uranyl Peroxide Capsule Fragments. Inorganic Chemistry , 59(3), 1633-1641. DOI: 10.1021/acs.inorgchem.9b02660

Archismita, Misra, Kozma, Karoly, Streb, Carsten, and Nyman, May. (2020) Beyond Charge Balance: Counter-Cations in Polyoxometalate Chemistry. Angewandte Chemie International Edition, 59, 596-612.  DOI: 10.1002/anie.201905600. 

 

2019

Mireia Segado, May Nyman, and Carles Bo. (2019) Aggregation Patterns in Low- and High-Charge Anions Define Opposite Solubility Trends. The Journal of Physical Chemistry B. 123, 10505-105013. DOI: 10.1021/acs.jpcb.9b08571

James A. Sommers, Danielle C. Hutchinson, Nicolas P Martin, Karoly Kozma, Douglas A Keszler, and May Nyman. (2019) Peroxide-Promoted Disassembly-Reassembly of Zr-Polyoxocations. Journal of the American Chemical Society, 141(42), 16894-16902. DOI: 10.1021/jacs.9b08627

Rebecca D. Stern, Danielle C. Hutchinson, Morgan R. Olsen, Lev N. Zakharov, May Nyman, and Kristin A. Persson. (2019) Alkyltin Keggin clusters as EUVL photoresist technology. International Conference on Extreme Ultraviolet Lithography 2019, 111471L. DOI: 10.1117/12.2538639

Rami J. Batrice, Jennifer N. Wacker, Elliot N. Glass, Safia Z. Jilani, Yu Ye J. Tong, May Nyman, and Karah E. Knope. (2019) Template-Free Cyclic Hexavanadate: Synthesis, Characterization, Solid-State Structure, and Solution-State Dynamics. Polyhedron, 169, 266-277. DOI: 10.1016/j.poly.2019.05.014

Karoly Kozma, Maoyu Wang, Pedro I. Molina, Nicolas P. Martin, Zhenxing Feng, and May Nyman. (2019) The role of titanium oxo-clusters in the sulfate process for TiO2 production. Dalton Transactions, 48(29), 11086-11093. DOI:10.1039/c9dt01337. 

Jennifer N. Wacker, Monica Vasiliu, Ian Colliard, R. Lee Ayscuelll, Sae Young Han, Jeffery A. Bertke, May Nyman, David A. Dixon, and Karah E. Knope. (2019) Monomeric and Trimeric Thorium Chlorides Isolated from Acidic Aqueous Solution. Inorganic Chemistry, 58(16) , 10871-10882. DOI: 10.1021/acs.inorgchem.9b01238.

Nicolas P. Martin, Enric Petrus, Miereia Segado, Ana Arteaga, Lev N. Zakharov, Carles Bo, and May Nyman. (2019) Strategic Capture of {Nb7} Polyoxometalate. Chemistry-A European Journal,  25, 10580-10584. DOI: 10.1002/chem.201902770 

Wei Wang, Mehran Amiri, Tao Huang, Leb N. Zakharov, Yining Zhang and May Nyman. (2019) Stabilizing Reactive Fe(III) Clusters by Freeze-Dry/Solvent-Exchange to Benchmark Iron Hydrolysis Pathways. Inorganic Chemistry,  58(9), 5555-5560. DOI:10.1021/acs.inorgchem.8b03446

Ana Arteaga, Lei Zhang, Sarah Hickman, Mateusz Dembowski, Peter C. Burns, and May Nyman. (2019) Uranyl-Peroxide Capsule Self-Assembly in Slow Motion. Chemistry-A European Journal,  25, 1-6 DOI: 10.1002/chem.201806227

Yu Zhu, Morgan Rose Olsen, Lei Zhang, Jian Zhang, and May Nyman. (2019) Stabilizing γ-Alkyltin-Oxo Keggin Ions by Borate Functionalization. Inorganic Chemistry,  58(7), 4534-4539, DOI: 10.1021/acs.inorgchem.9b00093.

Ryan T. Federick, J. Trey Diulus, Danielle C. Hutchison,  Gregory S. Herman, May Nyman. (2019) Effect of Oxygen on Thermal and Radiation-Induced Chemistries in a Model Organotin Photoresist. ACS Applied Materials Interfaces,  11(4), 4514-4522, DOI: 10.1021/acsami.8b16048

Omid Naderi, Mehran Amiri, Rahmat Sadeghi, May Nyman. (2019) Synthesis and Characterization of Silver Nanoparticles in Aqueous Solutions of Surface Active Imidazolium-based Ionic Liquids and Traditional Surfactants SDS and DTAB. Journal of Molecular Liquids, 2019, 273, 645-652 DOI: 10.1016/j.molliq.2018.10.046

Lei Zhang, Mateusz Dembowski, Ana Arteaga, Sarah Hickam, Nicolas P. Martin, Lev N. Zakharov, Peter C. Burns, May Nyman. (2019) Energetic Trends in Monomer Building Blocks for Uranyl Peroxide Clusters. Inorganic Chemistry, 58 (1), 439-445, DOI: 10.1021/acs.inorgchem.8b02661

Alexandra A. Shmakova, Victoria V. Volchek, Vadim Yanshole, Nikolay B. Kompankov, Nicholas P. Martin, May Nyman, Pavel A. Abramov, and Maxim N. Sokolov. (2019) Niobium uptake by a [P8W48O184]40- macrocyclic polyanion. New Journal of Chemistry, 43, 9943-9952. DOI: 10.1039/C9NJ01907C. 

J. Trey Diulus, Ryan T. Federick, Mengjun Li, Danielle C. Hutchison, Morgan R. Olsen, Igor Lyubinetsky, Líney Árnadóttir, Eric L. Garfunkel, Hirohito Ogasawara, Gregory S. Herman, May Nyman. (2019) Ambient-Pressure X-ray Photoelectron Spectroscopy Characterization of Radiation-Induced Chemistries of Organotin Clusters. ACS Applied Materials Interfaces, 11 (2), 2526-2534, DOI: 10.1021/acsami.8b19302

2018

Wei Wang, Mehran Amiri, Karoly Kozma, Jian Lu, Lev. N Zakharov, May Nyman. (2018) Reaction Pathway to the Only Open-Shell Transition-Metal Keggin Ion without Organic Ligation. European Journal of Inorganic Chemistry, 2018 (42), 4638-4642, DOI:/10.1002/ejic.201801087

Dylan J. Sures, G.P. Nagabhushana, Alexandra Navrotsky, and May Nyman. (2018) Thermochemical Measurements of Alkali Cation Association to Hexatantalate. Molecules, 23 (10), 2441, DOI: 10.3390/molecules23102441

Danielle C. Hutchison, Rebecca D. Stern, Morgan R. Olsen, Lev N. Zakharov, Kristin A. Persson, and May Nyman. (2018) Alkyltin clusters: the less symmetric Keggin isomers, Dalton Transactions, DOI: 10.1039/C8DT01950A

Dr. Clément Falaise, Karoly Kozma, May Nyman. (2018) Thorium Oxo-Clusters as Building Blocks for Open Frameworks. Chemistry A European Journal, 24 (53), 14226-14232, DOI: 10.1002/chem.201802671

Karoly Kozma, Todd Wesley Surta, Pedro I. Molina, Lgor Lyubinetsky, Wynn Stoxen, Nichole M. Byrne, Michelle Dolgos, May Nyman. (2018) Probing the local structure of crystalline NaBiO3·XH2O and its acidified derivatives, Journal of Solid State Chemistry DOI:10.1016/j.jssc.2018.04.012

Ryan T. Frederick, Jenn M. Amador, Sara Goberna-Ferrón, May Nyman, Douglas A. Keszler, and Gregory S. Herman. (2018) Mechanistic Study of HafSOx Extreme Ultraviolet Inorganic Resists. The Journal of Physcial Chemistry C, 122 (28), 16100-16112, DOI: 10.1021/acs.jpcc.8b03771

Nicole A, Vanagas, Jennifer N. Wacker, Christopher L. Rom, Elliot N. Glass, Ian Colliard, Yusen Qiao, Jeffery A. Bertke, Edward Van Keuren, Eric J. Schelter, May Nyman, and Karah E. Knope. (2018) Solution and Solid State Stuctural Chemistry of Th(IV) and U(IV) 4-Hydroxybenzoates. Inorganic Chemistry57 (12), 7259-7269, DOI: 10.1021/acs.inorgchem.8b00919

Jing Xie, Harrison A. Neal, Jennifer Szymanowski, Peter C. Burns, Todd M. Alam, May Nyman, and Laura Gagliardi. (2018) Resolving Confined 7Li Dynamics of Uranyl Peroxide Capsule U24.Inorganic Chemistry, 57 (9), 5514-5525, DOI: 10.1021/acs.inorgchem.8b00474

Omid Sadeghi, Mehran Amiri, Eric Reinheimer, and May Nyman. (2018) The role of Bi3+ in promoting and stabilizing Fe-oxo clusters in strong acid. Angewandte Chemie International Edition, DOI: 10.1002/anie.201802915

Peter C. Burns and May Nyman. (2018) Captivation with encapsulation: a dozen years of exploring uranyl peroxide capsules. Dalton Transactions, 47, 5916-5927, DOI: /10.1039/C7DT04245K

Ryan T. Frederick, J. Trey Diulus, Igor Lyubinetsky, Danielle C. Hutchison, Morgan R. Olsen, May Nyman, Gregory S. Herman. Surface characterization of tin-based inorganic EUV resists. In Proc. SPIE 10586: Advances in Patterning Materials and Processes XXXV, 105860K, SPIE Advanced Lithography, San Jose, California, March 13, 2018; DOI:10.1117/12.2297484

Menjun Li, Viacheskav Manichev, Fangzhou Yu, Danielle Hutchison, May Nyman, Torgny Gustafsson, Leonard C. Feldman, Eric L. Garfunkel. Novel Sn-based photoresist for high aspect ratio patterning. In Proc. SPIE 10586: Advances in Patterning Materials and Processes XXXV, 1058607, SPIE Advanced Lithography, San Jose, California, March 13, 2018; DOI:10.1117/12.2297440

Collin N. Muniz, Hiral Patel, Dylan B. Fast, Lauren R.S. Rohwer, Eric W. Reinheimer, Michelle Dolgos, Matt. W. Graham, and May Nyman. (2018) Rare earth niobate coordination polymers. Journal of Solid State Chemistry, 259, 48-56. DOI:10.1016/j.jssc.2017.12.034

2017

Pedro I. Molina, Karoly Kozma, Melissa Santala, Clément Falaise, May Nyman (2017). Aqueous Bismuth tianium-oxo sulfate cluster speciation and crystallization, Angewandte Chemie, 56(51) 16277-16281, DOI: 10.1002/anie.201709539

Sures, D. J., & Nyman, M. (2017). Anomalous Cesium Ion Behavior in Aqueous Polyoxometalate Solutions, Cesium: Properties, Production and Applications (119-148). Nova Science Pub Inc. Book Chapter PDF

Clément Falaise, Sarah M. Hickman, Peter C. Burns, and May Nyman (2017) From aqueous speciation to supramolecular assembly in alkaline earth-uranyl polyoxometalates, Chemical Communications, 53, 9550-9553. DOI:10.1039/C7CC05357F

Sumit Saha, Deok-Hie Park, Danielle C. Hutchison, Morgan R. Olsen, Lev N. Zakharov, David Marsh, Sara-Goberna-Ferrón, Ryan T. Frederick, J. Trey Diulus, Nizan Kenane, Gregory S. Herman, Darren W. Johnson, Douglas A. Keszler, May Nyman (2017) Alkyltin Keggin Clusters Templated by Na. Angewandte Chemie International Edition,56(34) 10140-10144: DOI: 10.1002/anie.201701703

May Nyman (2017) Small-angle X-ray scattering to determine solution speciation of metal-oxo clusters.  Coordination Chemistry Reviews. 352, 461-472, DOI: /10.1016/j.ccr.2016.11.014

Lauren B. Fullmer, Christopher E. Malmberg, Dylan B. Fast, Lindsay A. Wills, Paul Ha-Yeon Cheong, Michelle R. Dolgos, May Nyman (2017) Aqueous tantalum polyoxometalate reactivity with peroxide.  Dalton Transactions 46(26) 8486-8493. DOI: 10.1039/C7DT01478C

Cory K. Perkins, Eric S. Eitrheim, Brantly L. Fulton, Lauren B. Fullmer, Christopher A. Colla, Deok-Hie Park, Anna F. Oliveri, James E. Hutchison, May Nyman, William H. Casey, Tori Z. Forbes, Darren W. Johnson, Douglas A. Keszler (2017Synthesis of an Aluminum Hydroxide Octamer through a Simple Dissolution Method. Angewandte Chemie International Edition, 56(34) 10161-10164  DOI: 10.1002/anie.201702318

Clément Falaise, Harrison A. Neal, and May Nyman. (2017) U(IV) Aqueous Speciation from the Monomer to UO2 Nanoparticles: Two Levels of Control from Zwitterionic Glycine Ligands; Inorg. Chem., 56(11), 6591-6598,  DOI: 10.1021/acs.inorgchem.7b00616 

Dylan J. Sures, Stefano A. Serapian, Károly Kozma, Pedro I. Molina, Carles Bo, and May Nyman. (2017) Electronic and relativistic contributions to ion-pairing in polyoxometalate model systems, Journal of Physical Chemistry Chemical Physics. 19 (13), 8715-8725. http://pubs.rsc.org/en/content/articlelanding/2017/cp/c6cp08454k#!divAbstract
 
Nunu A.G. Bandeira, Omid Sadeghi, Toby J. Woods, Yuan-Zhu Zhang, Jurgen Schnack, Kim Dunbar, May Nyman and Carles Bo. (2017) Magneto-Structural Analysis of Iron (III) Keggin Polyoxometalates, Journal of Physical Chemistry A, 121 (6), 1310-1318. http://pubs.acs.org/doi/abs/10.1021/acs.jpca.6b10763
 
Lauren B. Fullmer and May Nyman. (2017) Probing Crystallization Pathways in Group V Polyoxometalate Solutions. Journal of Cluster Science, 28(2), 813-823. DOI: 10.1007/s10876-016-1106-8
 
David A. Marsh, Sara Goberna-Ferrón, Mary K. Baumeister, Lev N. Zakharov, May Nyman, Darren W. Johnson (2017) Ln polyoxocations: yttrium oxide solution speciation & solution deposited thin films. Dalton Transactions, 46, 947-955. 
DOI: 10.1039/C6DT03733J
 
Cory K Perkins, Ryan H Mansergh, Juan C Ramos, Charith E Nanayakkara, Deok-Hie Park, Sara Goberna-Ferrón, Lauren B Fullmer, Joshua T Arens, Maceo T Gutierrez-Higgins, Yolanda R Jones, Jonathon I Lopez, Thomas M Rowe, Danielle M Whitehurst, May Nyman, Yves J Chabal, Douglas A Keszler (2017) Low-index, smooth Al 2 O 3 films by aqueous solution process Optical Materials Express. 7(1) 273-280. https://doi.org/10.1364/OME.7.000273
 
Harrison Neal, Jennifer Szymanowski, Jeremy Fein, Peter Burns, and May Nyman. (2017) Benchmarking uranyl peroxide capsule chemistry in organic media. European Journal of Inorganic Chemistry. 1, 39-46  DOI: 10.1002/ejic.201601219

2016

Wei Wang, Lauren B. Fullmer, Nuno A.G. Bandeira, Lev Zakharov, Carles Bo, Doug Keszler, May Nyman (2016) Crystallizing Elusive Chromium Polycations. Chem. 1(6) 887-991
https://doi.org/10.1016/j.chempr.2016.11.006

Omid Sadeghi, Clément Falaise, Pedro I. Molina, Ryan Hufschmid, Charles F. Campana, Bruce C. Noll, Nigel D. Browning, and May Nyman. (2016) Chemical Stabilization and Electrochemical Destabilization of the Iron Keggin in Water. Inorganic Chemistry. 55: 11078-11088.  DOI: 10.1021/acs.inorgchem.6b01694

May Nyman (2016) Polyoxometalates and other metal-oxo clusters in nature. Springer Encyclopedia of Geochemistry. Publication date: August 30, 2016. DOI: 10.1007/978-3-319-39193-9_43-1 

Olivier Renier, Clément Falaise, Harrison Neal, Karoly Kozma, May Nyman. (2016) Closing Uranyl Polyoxometalate Capsules with Bismuth and Lead Polyoxocations. Angewandte Chemie International Edition. 55: 13480-13484. DOI: 10.1002/anie.201607151

Clément Falaise and May Nyman. (2016) The Key Role of U28 in the Aqueous Self-Assembly of Uranyl Peroxide Nanocages. Chemistry A European Journal. 22: 14678-14687. DOI:10.1002/chem.201602130

Dylan J. Sures, Sulata K. Sahu, Pedro I Molina, Alexandra Navrotsky, and May Nyman. (2016) Distinctive Interactions of Cesium and Hexaniobate in Water. Chemistry Select 1 (9): 1858-1862. DOI: 10.1002/slct.201600493
 
Pere Miró, Bess Vlaisavljevich, Adria Gil, Peter C. Burns, May Nyman, Carles Bo, C. (2016) Self‐Assembly of Uranyl–Peroxide Nanocapsules in Basic Peroxidic Environments. Chemistry A European Journal. 22: 8571-8578. DOI: 10.1002/chem.201600390
 
Todd M. Alam, Zuolei Liao, May Nyman, Jonathan R. Yates. (2016) Insight Into the Hydrogen Bonding of Uranyl Hydroxide Layers and Capsules Using 1H MAS NMR Spectroscopy. The Journal of Physical Chemistry C. 120 (19): 10675–10685 DOI: 10.1021/acs.jpcc.6b02692
 
Sara Goberna Ferron, Deok-Hie Park, Jenn M. Amador, Douglas A. Keszler, May Nyman. (2016) Amhpoteric Aqueous Hafnium Cluster Chemistry. Angewandte Chemie International Edition. 55: 6221-6224. DOI: 10.1002/anie.201601134
 
Ryan H. Mansergh, Lauren B. Fullmer, Deok-Hie Park, May Nyman, Douglas A. Keszler. (2016) Reaction Pathway: Aqueous Hexatantalate Clusters to High-Density Tantalum Oxide Nanofilms. Chemistry of Materials. 28(5): 1553-1558. DOI: 10.1021/acs.chemmater.6b00078

Dylan J. Sures, Pedro I. Molina, Pere Miro, Lev N. Zakharov, and May Nyman. (2016) Cesium salts of niobo-tungstate isopolyanions with intermediate group V -group VI character. New Journal of Chemistry. 40: 928-936. DOI: 10.1039/c5nj02914g

Tapash Deb, Lev Zakharov, Clément Falaise, and May Nyman. (2016) Structure and Solution Speciation of UIV Linked Phosphomolybate (Mo)v Clusters. Inorganic Chemistry. 55 (2): 755-761. DOI: 10.1021/acs.inorgchem.5b02229

 

2015

Cebollada,A., Vellé, A., Iglesias, M., Fullmer, L. B., Goberna-Ferron,S., Nyman, M. & Sanz Miguel, P.J., (2015) Direct X-Ray Scattering Evidence for Metal–Metal Interactions in Solution at the Molecular Level.  Angewandte Chemie. 127: 12953–12957. DOI: 10.1002/ange.201505736

Molina, P. I.; Sures, D. J.; Miro, P.; Zakharov, L. N.; Nyman, M. (2015). Bridging the opposite chemistries of tantalum and tungsten polyoxometalates. Dalton Transactions. 44: 15813-15822. DOI: 10.1039/C5DT02290H

 Jackson, M. N.; Kamunde-Devonish, M. K.; Hammann, B. A.; Wills, L. A.; Fullmer, L. B.; Hayes, S. E.; Cheong, P. H.-Y.; Casey, W. H.; Nyman, M.; Johnson, D.1W.  (2015). An overview of selected current approaches to the characterization of aqueous inorganic clusters. Dalton Transactions. 44: 16982-17006. DOI: 10.1039/C5DT01268F

Fullmer, L. B.; Mansergh, R. H.; Zakharov, L. N.; Keszler, D. A.; Nyman, M. (2015). Nb2O5 and Ta2O5 thin films from polyoxometalate precursors: A single proton makes a difference. Crystal Growth and Design. 15(8): 3885-3892. DOI: 10.1021/acs.cgd.5b00508

Nyman, M.; Fullmer, L. B. In Trends in Polyoxometalates Research; Ruhlmann, L.; Schaming, D., Eds.; Nova Science Publishers, Inc., (2015); pp. 151–170. Book Chapter PDF

Goberna-Ferrón, S., Soriano-López, J., Galán-Mascarós, J. R. and Nyman, M. (2015), Solution Speciation and Stability of Cobalt-Polyoxometalate Water Oxidation Catalysts by X-ray Scattering. Eur. J. Inorg. Chem. doi: 10.1002/ejic.201500404

Sadeghi, O; Zakharov, L. N.; Nyman, M.; (2015) Aqueous formation and manipulation of the iron-oxo Keggin ion. Science. 347 (6228), 1359-1362 doi: 10.1126/science.aaa4620 

Hou, Y.; Fast, D.B.; Ruther, R.R.; Amador, J. M.; Fullmer, L.B.; Decker, S.R.; Zakharov, L.N.; Dolgos, M.R.; Nyman, M.; (2015) "The atomic level journey from aqueous polyoxometalate to metal oxide". J. Solid State Chem., 418-425  doi:10.1016/j.jssc.2014.09.039

 

2014

Liao, Z., Deb, T., Nyman, M., (2014) Elucidating Self-Assembly Mechanisms of Uranyl-Peroxide Capsules from Monomers. Inorganic Chemistry. 53 (19), pp 10506–10513  DOI: 10.1021/ic501587g

Li, D., Simotwo, S., Nyman, M., et al., (2014) Evolution of Actinyl Peroxide Clusters U-28 in Dilute Electrolyte Solution: Exploring the Transition from Simple Ions to Macroionic Assemblies.Chemistry-A European Journal. 20(6), 1683-1690

Alam, T.M., Laio, Z., Zakharov, L.N., et al., (2014). Solid State Dynamics of Uranyl Polyoxometalates. Chemistry-A European Journal. 20(27) 8302-8307

Fullmer, L.B., Molina, P.I., Antonio, M.R., Nyman, M. (2014). Contrasting ion-association behavoir of Ta and Nb polyoxometalates. Dalton Transactions. doi:10.1039/C4DT02394C

Tiferet, E., Gil, A., Bo, C., Shvareva, T., Nyman, M., & Navrotsky, A. (2014). The Energy Landscape of Uranyl-Peroxide Species. Chemistry - A European Journal20(13), 3536. doi:10.1002/chem.201400426

Ruther, R. E., Baker, B. M., Son, J.-H., Casey, W. H., & Nyman, M. (2014). Hafnium Sulfate Prenucleation Clusters and the Hf18 Polyoxometalate Red Herring. Inorganic Chemistry53(8), 4234–4242. doi:10.1021/ic500375v

Kinnan, M. K., Creasy, W. R., Fullmer, L. B., Schreuder-Gibson, H. L., & Nyman, M. (2014). Nerve Agent Degradation with Polyoxoniobates. European Journal of Inorganic Chemistry, n/a–n/a. doi:10.1002/ejic.201400016

 Coltrin, M. E., Armstrong, A. M., Brener, I., Chow, W. W., Crawford, M. H., Fischer, A. J., … Wright, J. B. (2014). Energy Frontier Research Center for Solid-State Lighting Science: Exploring New Materials Architectures and Light Emission Phenomena. Journal of Physical Chemistry C, Ahead of Print. doi:10.1021/jp501136j

 

2013

Hou, Y., Fang, X., Kwon, K. D., Criscenti, L. J., Davis, D., Lambert, T., & Nyman, M. (2013). Computational and Experimental Characterization of a Cagelike Fe15 Polycation. European Journal of Inorganic Chemistry2013(10-11), 1780–1787. doi:10.1002/ejic.201201128

Hou, Y., Zakharov, L. N., & Nyman, M. (2013). Observing assembly of complex inorganic materials from polyoxometalate building blocks. Journal of the American Chemical Society135(44), 16651–7. doi:10.1021/ja4086484

Soylemez, E., de Boer, M. P., Sae-Ueng, U., Evilevitch, A., Stewart, T. A., & Nyman, M. (2013). Photocatalytic degradation of bacteriophages evidenced by atomic force microscopy. PLoS One8(1), e53601. doi:10.1371/journal.pone.0053601

 

2012

Nyman, M., & Burns, P. C. (2012). A comprehensive comparison of transition-metal and actinyl polyoxometalates. Chemical Society Reviews41(22), 7354–67. doi:10.1039/c2cs35136f

Nyman, M., & Alam, T. M. (2012). Dynamics of Uranyl Peroxide Nanocapsules. Journal of the American Chemical Society134(49), 20131–20138. doi:10.1021/ja308673f

Hou, Y., Rodriguez, M. A., & Nyman, M. (2012). Cation-Bonding and Protonation of the Fe4-Square Cluster. Crystal Growth & Design12(3), 1422–1431. doi:10.1021/cg2015397

Hou, Y., Alam, T. M., Rodriguez, M. a, & Nyman, M. (2012). Aqueous compatibility of group IIIA monomers and Nb-polyoxoanions. Chemical Communications, 6004–6006. doi:10.1039/c2cc31284k

Gil, A., Karhanek, D., Miro, P., Antonio, M. R., Nyman, M., & Bo, C. (2012). A Journey inside the U28 Nanocapsule. Chemistry - A European Journal18(27), 8340–8346, S8340/1–S8340/8. doi:10.1002/chem.201200801

 

Selected Publications from Sandia:

“Uranyl peroxide enhanced nuclear fuel corrosion in seawater”; Armstrong, Christopher R.; Nyman, May; Shvareva, Tatiana; Sigmon, Ginger E.; Burns, Peter C.; Navrotsky, Alex. Proceedings of the National Academy of Sciences, 109(6), 1874-1877, 2012. DOI: 10.1073/pnas.1119758109.

“The U28 Nanosphere:  What’s Inside?”  Nyman, May; Rodriguez, Mark A.; Alam, Todd M. European Journal of Inorganic Chemistry; 14, 2197-2205, 2011.  DOI: 10.1002/ejic.201001355 . cover feature

“Soluble Heteropolyniobates from the bottom of Group IA”; Hou, Yu; Nyman, May; Rodriguez, Mark A., Angew. Chem. Int. Ed., 52, 12514-12517, 2011.  DOI: 10.1002/anie.201104478. cover feature

“Polyoxoniobate Chemistry in the 21st Century”;  Nyman, May, Dalton Transac., 40(32), 8049-8058, 2011 DOI: 10.1039/c1dt10435g. cover feature

“Unique LaTaO4 Polymorph for Multiple Energy Applications”  Nyman, May; Rodriguez, Mark A.; Rohwer, Lauren E. S.; Martin, James E.; Waller, M.; Osterloh, Frank E. Chem. Mater. 21(19) 4731-4737, 2009.  DOI: 10.1021/cm9020645 Published: OCT 13 2009

“Highly Versatile Rare Earth Tantalate Pyrochlore Nanophosphors”  Nyman, May; Rodriguez, Mark A.; Shea-Rohwer, Lauren E.; Martin, James E.; Provencio, Paula P. J. Am. Chem. Soc. 131(33), 11652-11654, 2009.  DOI: 10.1021/ja903823w

“Enhanced Water Purification: A Single Atom Makes a Difference” Stewart, Tom A.; Trudell, Daniel E.; Alam Todd M.; Ohlin, C. Andre; Lawler, Christian; Casey, William H. Jett, Stephen, Nyman, May. Env. Sci Tech. 43(14), 5416-5422, 2009.  DOI: 10.1021/es803683t. featured in C&E News Science Concentrates

“Direct Observation of Contact Ion-Pair Formation in Aqueous Solution”  Antonio, Mark R.; Nyman, May; Anderson, Travis M.Angew. Chem. Int. Ed. 48(33) 6136-6140, 2009,  DOI: 10.1002/anie.200805323. cover feature

“An aqueous route to [Ta6O19]8- and solid-state studies of isostructural niobium and tantalum oxide complexes”  Anderson, Travis M.; Rodriguez, Mark A.; Bonhomme, Francois; Bixler, Joel N.; Alam, Todd M.; Nyman, May.  Dalton Transac. 40, 4517-4522,2007, DOI: 10.1039/b707636c. cover feature.

“A family of peroxo-titanate materials tailored for optimal strontium and actinide sorption”,  Nyman May; Hobbs David T.Chem. Mater. 18(26), 6425-6435, 2006;  DOI: 10.1021/cm061797h.

“A General Synthetic Procedure for Heteropolyniobates”  Nyman, May et al. Science, 297(5583), 996-998, 2002; DOI: 10.1126/science.1073979 Published.

 

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